In addition to getting on base, one of the jobs of the lead-off hitter is to make the pitcher throw a lot of pitches. This allows the subsequent batters to get an idea of the opposing pitcher's stuff that game . Here are all the lead-off plate appearance since 1988 that were 13 pitches of longer:

  Date           Batter         Tm   Opp  Pitcher                Score        Inn RoB Out Cnt Pit RBI Play Desc.
-------------+-----------------+---+----+-----------------+-----------+---+---+---+---+---+---+-------------------------+
1988-06-07    Brian Downing     CAL @TEX Charlie Hough     tied   0-0  SO     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Strikeout Swinging
1989-06-07    Howard Johnson    NYM @CHC Rick Sutcliffe    tied   0-0  2B     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Double to RF (Line Drive to Deep RF)
1989-06-23    Dave Martinez     MON @CHC Mike Bielecki     tied   0-0  HR     t 1 ---   0 3-2  15   1 *LEADOFF GM*:Home Run (Fly Ball to Deep CF-RF)
1990-05-27    Wade Boggs        BOS @MIN Kevin Tapani      tied   0-0  BB     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Walk
1990-06-30    Dwight Smith      CHC @SDP Andy Benes        tied   0-0  SO     t 1 ---   0 3-2  14   0 *LEADOFF GM*:Strikeout Looking
1991-10-05    Paul Molitor      MIL @BOS Tom Bolton        tied   0-0  BB     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Walk
1992-09-26    Pat Listach       MIL  OAK Ron Darling       tied   0-0  BB     b 1 ---   0 3-2  17   0 Walk
1993-08-23    Wade Boggs        NYY @CHW Jason Bere        tied   0-0  1B     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Single to CF (Line Drive to Deep SS-2B)
1996-08-25    Wayne Kirby       LAD  NYM Pete Harnisch     tied   0-0  BB     b 1 ---   0 3-2  13   0 Walk
1998-06-18    Johnny Damon      KCR @DET Justin Thompson   tied   0-0  SO     t 1 ---   0 2-2  13   0 *LEADOFF GM*:Strikeout Swinging
1998-06-30    Johnny Damon      KCR @STL Manuel Aybar      tied   0-0  SO     t 1 ---   0 3-2  15   0 *LEADOFF GM*:Strikeout Swinging
2000-08-14    Tony Womack       ARI @PHI Kent Bottenfield  tied   0-0  Out    t 1 ---   0 3-2  14   0 *LEADOFF GM*:Groundout: 3B-1B
2001-06-10    Jose Offerman     BOS  PHI Robert Person     down   0-1  Out    b 1 ---   0 3-2  13   0 Popfly: 3B
2003-09-25    Scott Podsednik   MIL @HOU Tim Redding       tied   0-0  SO     t 1 ---   0 2-2  14   0 *LEADOFF GM*:Strikeout Looking
2004-04-23    Mark Kotsay       OAK  ANA Jarrod Washburn   down   0-2  BB     b 1 ---   0 3-2  13   0 Walk
2004-09-02    Aaron Miles       COL @SFG Jason Schmidt     tied   0-0  SO     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Strikeout Swinging
2005-07-01    Scott Podsednik   CHW @OAK Rich Harden       tied   0-0  BB     t 1 ---   0 3-2  13   0 *LEADOFF GM*:Walk
2006-04-14    Cory Sullivan     COL  PHI Ryan Madson       down   0-1  Out    b 1 ---   0 3-2  13   0 Flyball: LF (Deep LF)
2007-08-19    Matt Stairs       TOR  BAL Jeremy Guthrie    tied   0-0  Out    b 1 ---   0 3-2  13   0 Flyball: CF (Deep CF)
2009-05-20    Chone Figgins     LAA @SEA Chris Jakubauska  tied   0-0  Out    t 1 ---   0 3-2  13   0 *LEADOFF GM*:Groundout: 2B-1B

• Wade Boggs, Johnny Damon and Scott Podsednik each pulled it off twice. Damon's two at-bats accounted for half of the strike-out swingings on the list.
• Pat Listach ran up the highest pitch total with 17, but Dave Martinez , who had the second longest at bat, wins the prize for homering on the 15th pitch.
• Damon(1) and Podsednik(1) didn't even make it to 3 ball counts.
• In total the players went 3-14 with a double, homer, 6 walks and 6 strikeouts.

The information in this post was collected from a series of "team batting event finder" searches.
Selecting 1st inning, 0 out, no runners on base,  batting 1st and 7+ pitches and searching for
Plate Appearances for all teams will give you an easy to scan list of long lead-off at bats.
(Selecting "Leading off the Game" will give you a similar list, but will only include visiting players.)

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